The solubility of AgCl in aqueous solutions is determined by the equilibrium between solid silver chloride (AgCl) and its ionic species. In a 0.100 M AgNO3 solution, when enough sodium chloride (NaCl) has been added to raise the concentration to 0.500 M, it is necessary for there to be enough NH3 present in order for the precipitation of AgCl to be prevented. This means that the NH3 concentration must be sufficient in order to maintain the equilibrium between solid silver chloride and its ionic species, thus preventing its precipitation from occurring due to an increase in ionic strength or saturation level being exceeded.
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